The rate of decomposition of tert-amyl nitrite (t-AmONO) has been studied in the absence (120"-155Β°C) and presence (16Oo-190"C) of nitric oxide. In the absence of nitric oxide for low concentrations of tert-amyl nitrite (-10-4M) and small extents of reaction (-l%), the first-order homogeneous rates
The dynamics of the photolysis of alkyl nitrites from a dielectric surface. A comparison with gas phase results
β Scribed by C.J.S.M. Simpson; P.T. Griffiths; M. Towrie
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 378 KB
- Volume
- 234
- Category
- Article
- ISSN
- 0009-2614
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Although our pyrolytic studies of five alkyl nitrites (RONO) have shown that it is possible to determine precise, acceptable values for k 1: (0 RONO -RO + NO we have been uncertain about the mechanism for the first order production of nitroxyl from primary and secondary nitrites. Nitroxyl could ari
During AC laser (IV3 nm) pllotolysis of11N3. a spcctrun~ of the emission from tlic Iiighly forbidden NH(a'A + X 3Z3 trmsition has beeri dctectcd. 13)' observing tile diuppcarance of this emission, tllc NH(a ' A) radicals were found to decay witli rates fxtcr than 33 s-l in tllis pllotolvsis s~stum.