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The gas-phase pyrolysis of alkyl nitrites VI. t-Amyl nitrite

✍ Scribed by L. Batt; T. S. A. Islam; G. N. Rattray

Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
514 KB
Volume
10
Category
Article
ISSN
0538-8066

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✦ Synopsis

The rate of decomposition of tert-amyl nitrite (t-AmONO) has been studied in the absence (120"-155Β°C) and presence (16Oo-190"C) of nitric oxide. In the absence of nitric oxide for low concentrations of tert-amyl nitrite (-10-4M) and small extents of reaction (-l%), the first-order homogeneous rates of acetone formation are a direct measure of reaction (1) since

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