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The gas-phase pyrolysis of alkyl nitrites. IV. Ethyl nitrite

✍ Scribed by L. Batt; R. T. Milne

Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
673 KB
Volume
9
Category
Article
ISSN
0538-8066

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✦ Synopsis

The rate of decomposition of ethyl nitrite (EN) has been studied in a static system over the temperature range of 162-218Β°C. The main products are formaldehyde, acetaldehyde, ethanol, and nitrous oxide. For low concentrations of EX (10-5-10-4M), but with a high total pressure of CF, (-0.9 atm) and small extents of reaction (2-60/,), the first-order homogeneous rates of CHZO formation are a direct measure of reaction (l), since k3b >> k z ( X O ) :

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