The dynamics of CO production from the O(3P) + methylacetylene reaction
โ Scribed by M.E. Umstead; R.G. Shortridge; M.C. Lin
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 613 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0301-0104
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๐ SIMILAR VOLUMES
The reactions of O(3P) atoms with allene and mcthylacetylcne: 0 + CH2=C=CHL 5 CO +C2HG, a@ = -119.4 kcal/mole, 0 + CH3-GCH 2 CO + C,E&,, 44 = -1!7.8 kcd/mole were studied at 293 K with a CO kser resonant absorption and ZI dischzqe-flow CC-sampling method. The CO formed in rcacrion (1) wax ibund to h
the formation of higher oxides of chlorine such as Cl 2 O 4 , Cl 2 O 6 , and Cl 2 O 7 has been observed [5 -8]. The reaction mechanisms are not understood but may involve the formation of ClO 3 which has recently been observed in an inert matrix [9]. In these systems, ClO 3 can be formed via the add
The rate constant for the reaction of O(") with H202 was measured as a function of temperature and the [H202]0/[0]0 ratio. The numerical solution of the appropriate rate equations was used to arrive a t a mechanism which adequately describes our results and the rather divergent data in the literatur