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The dynamics of CO production from the O(3P) + methylacetylene reaction

โœ Scribed by M.E. Umstead; R.G. Shortridge; M.C. Lin


Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
613 KB
Volume
20
Category
Article
ISSN
0301-0104

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๐Ÿ“œ SIMILAR VOLUMES


The dynamics of reactions of O(3P) atoms
โœ M.C. Lin; R.G. Shortridge; M.E. Umstead ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 552 KB

The reactions of O(3P) atoms with allene and mcthylacetylcne: 0 + CH2=C=CHL 5 CO +C2HG, a@ = -119.4 kcal/mole, 0 + CH3-GCH 2 CO + C,E&,, 44 = -1!7.8 kcd/mole were studied at 293 K with a CO kser resonant absorption and ZI dischzqe-flow CC-sampling method. The CO formed in rcacrion (1) wax ibund to h

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the formation of higher oxides of chlorine such as Cl 2 O 4 , Cl 2 O 6 , and Cl 2 O 7 has been observed [5 -8]. The reaction mechanisms are not understood but may involve the formation of ClO 3 which has recently been observed in an inert matrix [9]. In these systems, ClO 3 can be formed via the add

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The rate constant for the reaction of O(") with H202 was measured as a function of temperature and the [H202]0/[0]0 ratio. The numerical solution of the appropriate rate equations was used to arrive a t a mechanism which adequately describes our results and the rather divergent data in the literatur