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The doublet structure of the DF-ODMR signals of triplet excitons in anthracene/TCNB

✍ Scribed by J.U. Von Schütz; W. Steudle; H.C. Wolf; P. Reineker; U. Schmid

Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 333 KB
Volume: 79
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(81)85275-x

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✦ Synopsis

DF-ODMF. signals (zero-field magnetic resonance detected by delayed fluorescence) of metastable trlplet excltons m the l-1 CT crystal anthracene/tetracyanobenzene are doublets wth a sphttlng of 10 MHz Thus structure IS a conseqoznce of Davydov sphttmg due to mterchain ewhangeJb. The best fit gves J6 = 0 011 cm-' and euxton zero-field sphrun_es D = 2019 5, E = -248 MHz

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