Several isomolecular gaseous eo\_uilibria involving A10 and Ala0 were studied by mass spectrometry, and the resuIts were used :o derive the dissociation energies of the two molecular species. Good internal agreement was obtained among the various experiments, leading to DE (AIO) = 118.6 +-2.5 kcal a
The dissociation energies of the molecules PtC and RhC
โ Scribed by A. Vander Auwera-Mahieu; J. Drowart
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- English
- Weight
- 220 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The disswiation energies of the gaseous molecules PtC and RhC were determined: Dg(PtC) = = 145.3 f 1.5: Dg(RbC) = 138.5 * 1.5 kcai/mole.
๐ SIMILAR VOLUMES
Ihe gaseous equiLiirium S + CF2 = SF + CF was studied over the temperature range 18.5 L to 2232 K by mzss spectiemetry, and the derived enthalpy change was used to evaluate the heat of formation of CF AH&g8 = 58.0 + 2.4 kcal/mol (2.3& f 0.10 eV), and the dissotition energy Dt(C\_F) = 130.8 r 2.4 kca
Simple inequalities satisfied by the dissociation energy of the excitonic molccuIa are derived. They provide a useM check on the validity of calculated dissociation cncr@x. Recently, increasing interest has been attached to the excitonic moIecule, a complex consisting of two electrons and two posit