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Dissociation energies of the molecules AlO and Al2O

✍ Scribed by D.L. Hildenbrand

Publisher: Elsevier Science
Year: 1973
Tongue: English
Weight: 275 KB
Volume: 20
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(73)85236-4

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✦ Synopsis

Several isomolecular gaseous eo_uilibria involving A10 and Ala0 were studied by mass spectrometry, and the resuIts were used :o derive the dissociation energies of the two molecular species. Good internal agreement was obtained among the various experiments, leading to DE (AIO) = 118.6 +-2.5 kcal and 0: (AlaO) = 249.0 * 5.6 kcal. From electron impact measurements, the ionization potentials were found to bc IP(AI0) = 9.53 eV and Ip(A120) = 8.20 eV with uncertainties of 0.15eV. The results xc discussed in relation to other information in the litcraturc.

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