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The disposition of allyl isothiocyanate in the rat and mouse

โœ Scribed by M. Bollard; S. Stribbling; S. Mitchell; J. Caldwell


Book ID
117450676
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
729 KB
Volume
35
Category
Article
ISSN
0278-6915

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The mechanism of isomerization of allyl thiocyanate to allyl isothiocyanate has been investigated both experimentally and theoretically. The kinetic study indicates that the reaction is unimolecular and is not ionic. The entropy of activation suggests strongly that the mechanism involves a cyclic tr