The diffusion coefficient of chlorine atoms Cl(3p5(2PJ)) in the gas phase
✍ Scribed by J.C. André; J.Y. Jezequel; R.H. Clark; D. Husain
- Publisher
- Elsevier Science
- Year
- 1980
- Weight
- 461 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0047-2670
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The dispersion of a pulse of O(3P) atoms in flowing helium has been analyzed by a modification of Taylor's method in order to determine the diffusion coefficient. Atoms of O(3P) were produced in a flowing stream of helium by a pulsed microwave discharge of molecular oxygen. After traversing a known
The following reactions: (1, -1) . CF, + CzFSC1 CF&l + ' CzF5 (2) (3) were studied over the temperature ranges 533-687 K, 563-663 K, and 503-613 K for the forward reactions respectively and over 683-763 K, for the back reaction. Arrhenius parameters for chlorine atom transfer were determined re
## Abstract Rate coefficients, __k__, for the gas‐phase reaction of O(^3^P) atoms with Cl~2~O (dichlorine monoxide) over a range of temperatures (230–357 K) at pressures between 12 and 32 Torr (N~2~) are reported. Rate coefficients were measured under pseudo‐first‐order conditions in O(^3^P) using