𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Rate coefficients for the O(3P) + Cl2O gas-phase reaction between 230 and 357 K

✍ Scribed by Dimitrios K. Papanastasiou; James B. Burkholder

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
241 KB
Volume
43
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Rate coefficients, k, for the gas‐phase reaction of O(^3^P) atoms with Cl~2~O (dichlorine monoxide) over a range of temperatures (230–357 K) at pressures between 12 and 32 Torr (N~2~) are reported. Rate coefficients were measured under pseudo‐first‐order conditions in O(^3^P) using pulsed laser photolysis to produce O(^3^P) atoms and atomic resonance fluorescence to detect its temporal profile. The rate coefficient temperature dependence is given by the Arrhenius expression k(T) = (1.51 ± 0.20) × 10^−11^ exp[−(477 ± 30)/T] cm^3^ molecule^−1^ s^−1^, and k(296 K) was measured to be (2.93 ± 0.30) × 10^−12^ cm^3^ molecule^−1^ s^−1^. The quoted uncertainty limits are at the 2σ (95% confidence) level and include estimated systematic errors. The rate coefficients determined in the present study, under conditions that minimized secondary losses of O(^3^P), are compared with previous results from other laboratories and the discrepancies are discussed. © 2011 Wiley Peiodicals, Inc.*This article is a U.S. Government work and, as such, is in the public domain of the United States of America.

Int J Chem Kinet 43: 312–321, 2011

📜 SIMILAR VOLUMES

The rate coefficient for the reaction of
The rate coefficient for the reaction of O(3P) with CH3OOH at 297 K
✍ Ghanshyam L. Vaghjiani; A. R. Ravishankara 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 489 KB

The absolute second-order rate coefficient for the reaction, O(3P) + CH300H + products, was measured to be ki = (1.06 ? 0.26) x cm3 molec-' s-l at 297 K, where the quoted error is 2 a including precision and estimated systematic errors. The possible presence of (CH3CHp),0 in our sample of CH,OOH lea

Discharge flow-chemiluminescence study o
Discharge flow-chemiluminescence study of the rate coefficients for O(3P) + CF2CCl2 and O(3P) + CF3CFCF2 reactions at 298 K
✍ M. A. Teruel; R. A. Taccone; S. I. Lane 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 93 KB 👁 2 views

The kinetics of the reactions O( 3 P) ϩ CF 2 "CCl 2 and O( 3 P) ϩ CF 3 CF "CF 2 were studied at room temperature in a discharge flow tube system. The overall rate constants based on the measured afterglow reactions were (3.10 Ϯ 0.40) ϫ 10 Ϫ13 and (3.00 Ϯ 0.60) ϫ 10 Ϫ14 cm 3 molecule Ϫ1 s Ϫ1 , respec

Rate coefficients for the gas-phase reac
Rate coefficients for the gas-phase reaction of isoprene with NO3 and NO2
✍ Jeanette R. Stabel; Matthew S. Johnson; Sarka Langer 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 207 KB 👁 1 views

## Abstract Rate coefficients for the gas‐phase reaction of isoprene with nitrate radicals and with nitrogen dioxide were determined. A Teflon collapsible chamber with solid phase micro extraction (SPME) for sampling and gas chromatography with flame ionization detection (GC/FID) and a glass reacto

Rate coefficients for the reaction of th
Rate coefficients for the reaction of the acetyl radical, CH3CO, with Cl2 between 253 and 384 K
✍ T. Gierczak; B. Rajakumar; Jonathan E. Flad; James B. Burkholder 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 295 KB

## Abstract Rate coefficients, __k__, for the gas‐phase reaction CH~3~CO + Cl~2~ → products (2) were measured between 253 and 384 K at 55–200 Torr (He). Rate coefficients were measured under pseudo‐first‐order conditions in CH~3~CO with CH~3~CO produced by the 248‐nm pulsed‐laser photolysis of acet

Rate constants for the gas-phase reactio
Rate constants for the gas-phase reactions of O3 with selected organics at 296 K
✍ Roger Atkinson; Sara M. Aschmann; Dennis R. Fitz; Arthur M. Winer; James N. Pitt 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 English ⚖ 299 KB 👁 1 views

## Abstract Rate constants for the gas‐phase reactions of O~3~ with ethene, propene, 1‐hexene, 1‐heptene, styrene, __o__‐, __m__‐, and __p__‐cresol, __o__‐ and __m__‐xylene, benzylchloride, acrylonitrile, and trichloroethene have been determined at 296 ± 2 K. The rate constants ranged from <5 × 10^