## Abstract The nonionic surfactants polyoxyethylene nonyl phenol ethers have been used as models for the investigation of the change of the effective HLB of surfactants under influence of several hydroxy compounds using the phenol index method. These waterβsoluble additives include alcohols, glyco
The Determination of the Effective HLB of Nonionic Surfactants by a Phenol Titration I: Relation to Cloud Point
β Scribed by Marszall, L.
- Publisher
- John Wiley and Sons
- Year
- 1980
- Weight
- 613 KB
- Volume
- 82
- Category
- Article
- ISSN
- 0931-5985
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β¦ Synopsis
Abstract
The qualitative similarities in two various methods of the HLB (HydrophileβLipophile Balance) determination based on the cloud point and so called phenol index measurements are demonstrated. The effects of polyoxyethylene chain length, surfactant concentration and the presence of additives on the cloud point and phenol index values have been compared. The results are interpreted as the change of the effective HLB of polyoxyethylene nonionic surfactants.
π SIMILAR VOLUMES
The surface-chemical properties, critical micelle concentrations (CMC), and effect of salts on the cloud points (CP) of octoxynol 9 (Triton X-100) and tyloxapol (Triton WR-1339) were compared. The latter nonionic surfactant is essentially a heptamer of the former. Even though the molecular weight of