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The deprotonation of trialkylamine cation radicals by amines

โœ Scribed by Nelsen, Stephen F.; Ippoliti, J. Thomas.


Book ID
126818739
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
412 KB
Volume
108
Category
Article
ISSN
0002-7863

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Neutral radicals are observed at 77 K following radiolysis of cycloheptatriene and cyclohexane adsorbed on ZSM-5 zeolites. The mechanism of radical formation is assigned to proton transfer from the sorbate radical cations to the zeolite lattice. In the case of cycloheptatriene, the ratio C,H;/C,H,+'