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Efficient Unimolecular Deprotonation of Aniline Radical Cations

โœ Scribed by Dombrowski, Gary W.; Dinnocenzo, Joseph P.; Zielinski, Paul A.; Farid, Samir; Wosinska, Zofia M.; Gould, Ian R.

Book ID
125330697
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
230 KB
Volume
70
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

Deprotonation of hydrocarbon radical cat
Deprotonation of hydrocarbon radical cations in zeolites
โœ D.W. Werst; E.A. Piocos; E.E. Tartakovsky; A.D. Trifunac ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 697 KB

Neutral radicals are observed at 77 K following radiolysis of cycloheptatriene and cyclohexane adsorbed on ZSM-5 zeolites. The mechanism of radical formation is assigned to proton transfer from the sorbate radical cations to the zeolite lattice. In the case of cycloheptatriene, the ratio C,H;/C,H,+'