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The Decomposition of Gaseous Chloroformates. II. Substitution and Elimination Stereochemistry 1

✍ Scribed by Lewis, Edward S.; Herndon, William C.; Duffey, Donald C.


Book ID
126414420
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
414 KB
Volume
83
Category
Article
ISSN
0002-7863

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Competitive 1,2- and 1,3-hydride shifts
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Many examples of rearrangement which occur in straight-chain alkyl groups during kinetically controlled substitutions can be formally represented as proceeding via successive 1,2-shifts in intermediate carbonium ions.' -In certain cases, this mechanism has been