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Kinetics and mechanism of the decomposition of 1-adamantyl chloroformate

โœ Scribed by Kevill, Dennis N.; Weitl, Frederick L.

Book ID
127061568
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
632 KB
Volume
90
Category
Article
ISSN
0002-7863

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Competing solvolysis-decomposition of 1-
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โœ Dennis N. Kevill; Frederick L. Weitl ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 204 KB

Recently. the preparation of I-pdprantyl chlorofoxmate was reported2 and the decaqosition of compouud to yield I-adamaatyl chl oride has been studied3. The kiuetic procedure was to bydrothe mmmcted chloroformate ester in aqueous acetone aud titrate against rthauolic sodim methoxide. The 1-adamantyl

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The homogeneous gas-phase decomposition kinetics of silane has been investigated using the single-pulse shock tube comparative rate technique (T = 1035-1184ยฐK, P ~d = 4000 Torr). The initial reaction of the decomposition SiH4 ! + SiHz + H2 is a unimolecular process in its pressure fall-off regime w

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The homogeneous gas-phase thermal decomposition kinetics of germane have been measured in a single-pulse shock tube between 950 and 1060 K at pressures around 4000 torr. The initial decomposition is GeH4 -GeH2 + H2 in its pressure-dependent regime, with log k ~~~~( 4 m ) = 13.83 f 0.78 -50,750 f 357