The decay of solvated electrons in irradiated liquid alcohols
β Scribed by J.H. Baxendale; P. Wardman
- Publisher
- Elsevier Science
- Year
- 1984
- Weight
- 413 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0146-5724
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π SIMILAR VOLUMES
Using the techniques of pulse radiolysis a short-lived transient absorbing species (Xrnax = 1500 run] has been observed in liquid hydrocarbons at 193%. This absorption has been assigned to a trapped or sofvated electron and a&olute reaction rates have been obtained for reactions of sohated electrons
The ratc of disappearance of solvated electrons by reaction with fluorobcnzcne in ammonia is acce!erated by smal1 conccntrations of methanol; it also bas a "negative activation energy" depending on the methanol concentration. The kinetic dota suggest an csothermic electron attachment-detachment equi