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Kinetics of the reaction of solvated electrons with fluorobenzene in liquid ammonia

✍ Scribed by E. San Roman; P. Krebs; U. Schindewolf

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 293 KB
Volume: 49
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(77)80449-1

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✦ Synopsis

The ratc of disappearance of solvated electrons by reaction with fluorobcnzcne in ammonia is acce!erated by smal1 conccntrations of methanol; it also bas a "negative activation energy" depending on the methanol concentration. The kinetic dota suggest an csothermic electron attachment-detachment equilibrium with the fluorobenzene followed by a slower reaction of the electron adduct with the proton donating methanol.

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