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Pulse radiolysis observations of solvated electrons in liquid hydrocarbons

โœ Scribed by J.H. Baxendale; C. Bell; P. Wardman

Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
203 KB
Volume
12
Category
Article
ISSN
0009-2614

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๐Ÿ“œ SIMILAR VOLUMES

Direct observations of solvated electron
Direct observations of solvated electrons in liquid hydrocarbons
โœ J.T. Richards; J.K. Thomas ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 503 KB

Using the techniques of pulse radiolysis a short-lived transient absorbing species (Xrnax = 1500 run] has been observed in liquid hydrocarbons at 193%. This absorption has been assigned to a trapped or sofvated electron and a&olute reaction rates have been obtained for reactions of sohated electrons

Electron solvation in alcohols at 77 K a
Electron solvation in alcohols at 77 K after pulse radiolysis
โœ J.H. Baxendale; P.H.G. Sharpe ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 343 KB

The presence of benzyl in I-propanol, 2-propanal and ethanol glasses at 77 K markedly affects the' changes' which occur in the absorption spectra of the trapped electrons in the pure alcohols after their production by pulse radiolysis. The well known growth in the visible is considerably reduced whi

Production of solvated electrons, ion-pa
Production of solvated electrons, ion-paris and alkali metal anions in tetrahydrofuran studied by pulse radiolysis
โœ G.A. Salmon; W.A. Seddon ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 520 KB

## Pulse radiolysis of tetrahydrofuran (THF) and solutions of NaAlH4 in THF shows the formation of solvated elections (es). their conversion to (Na+-es) ion-pairs and ultimately the alkali metal anion (Na-). Although the spectrum of Na-has been characterized Extensive studies on solutions of alka