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Production of solvated electrons, ion-paris and alkali metal anions in tetrahydrofuran studied by pulse radiolysis

✍ Scribed by G.A. Salmon; W.A. Seddon

Publisher: Elsevier Science
Year: 1974
Tongue: English
Weight: 520 KB
Volume: 24
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(74)85279-6

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✦ Synopsis

Pulse radiolysis of tetrahydrofuran (THF) and solutions of NaAlH4 in THF shows the formation of solvated elections (es). their conversion to (Na+-es) ion-pairs and ultimately the alkali metal anion (Na-).

Although the spectrum of Na-has been characterized

Extensive studies on solutions of alkali metals in amines and ethers have indicated the presence of three in Na/K alloy solutions in THF [6] and also in potas-types of species, solvated electrons e;, an alkali

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## Abstract The solvation structure of magnesium, zinc(II), and alkaline earth metal ions in __N__,__N__‐dimethylformamide (DMF) and __N__,__N__‐dimethylacetamide (DMA), and their mixtures has been studied by means of Raman spectroscopy and DFT calculations. The solvation number is revealed to be 6