The dealkylation of 2-diethylamino-3H-phenothiazin-3-one
✍ Scribed by Yoshio Ueno
- Publisher
- Springer Vienna
- Year
- 1982
- Tongue
- English
- Weight
- 119 KB
- Volume
- 113
- Category
- Article
- ISSN
- 0026-9247
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## Abstract Die 2‐Dialkylamino‐3H‐phenoxazin‐3‐one **1** wurden durch Photolyse oder Pyrolyse zu 2‐Alkylamino‐3H‐phenoxazin‐3‐onen **2** entalkyliert.
In the title compound, C 21 H 21 N 3 O 2 , the three fused rings of the 1-benzofuro[3,2-d]pyrimidine system are almost coplanar. The packing of the molecules in the crystal structure is mainly governed byinteractions.
Two different syntheses of (z), one labeled with carbon-14 in the quinonoid ring and the other in the phenyl ring are described. methoxy benzenethiol yielded ( I ) , which was methoxylated to provide a mixture of isomers (&) and (8). isomers followed by bromination of (2) gave (2). Thiocyanation of