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The reactivity of the anion of 2-(diethylamino)-5-phenyl-3H-azepine. Synthesis of 3-substituted 2-(diethylamino)-5-phenyl-3H-azepines

โœ Scribed by J. W. Streef; H. C. van der Plas; A. van Veldhuizen; K. Goubits

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
761 KB
Volume
103
Category
Article
ISSN
0165-0513

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๐Ÿ“œ SIMILAR VOLUMES

Azepines.I : The formation and reactivit
Azepines.I : The formation and reactivity of the anion of 2-diethylamino-5-phenyl-3H-azepine
โœ J.W. Streef; H.C. van der Plas ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 190 KB

Swmary: Deprotonation of 2-diethyIumino-5-phenyZ-3!-azepine with strong bases affords a highZy coloured anion, which reacts with deuterim oxide or with an appropriate electrophile to give an azepine bearing the new substituent at C-3. During the last decades several papers have appeared dealing wit