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The curtius rearrangement of isomeric cycloheptatrienecarboxylic and norcaradienecarboxylic acids

✍ Scribed by D. N. Kursanov; M. E. Volpin; I. S. Akhrem; I. Ya. Kachkurova


Book ID
112491356
Publisher
Springer
Year
1957
Tongue
English
Weight
621 KB
Volume
6
Category
Article
ISSN
1573-9171

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A facile synthesis of primary amines fro
✍ Todd L. Capson; C.Dale Poulter πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 French βš– 197 KB

Ab4tic.Z . 2-Trimethylsilylethanol was used to trap isocyanates produced by the Curtius rearrangement of acyl azides and the resulting trimethylsilylethyl carbamates were readily cleaved with tetra-n-butylammonium fluoride to liberate the primary amines.