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A facile synthesis of primary amines from carboxylic acids by the curtius rearrangement

✍ Scribed by Todd L. Capson; C.Dale Poulter

Publisher: Elsevier Science
Year: 1984
Tongue: French
Weight: 197 KB
Volume: 25
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)91063-9

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✦ Synopsis

Ab4tic.Z . 2-Trimethylsilylethanol was used to trap isocyanates produced by the Curtius rearrangement of acyl azides and the resulting trimethylsilylethyl carbamates were readily cleaved with tetra-n-butylammonium fluoride to liberate the primary amines.

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