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The Cu(II)-nitroxyl radicals system: the high activity and reactivation of the catalyst in the decomposition of hydroperoxides

✍ Scribed by A. B. Gagarina; L. A. Smurova; E. N. Degtyarev; A. G. Kozyreva


Book ID
111472581
Publisher
Pleiades Publishing
Year
2009
Tongue
English
Weight
286 KB
Volume
3
Category
Article
ISSN
1990-7931

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Kinetic relationships for the decomposit
✍ T. V. Sirota; O. T. Kasaikina; A. B. Gagarina πŸ“‚ Article πŸ“… 1980 πŸ› Springer 🌐 English βš– 441 KB

Aliphatic radicals, particularly 2,2,6,6-tetramethylpiperidin-l-oxyl, react with alkyl radicals [I]. Nitroxyls containing aromatic substituents at the N atom also react with other types of radicals. For example,4;2',2,3, is an effective scavenger of alkyl, peroxy, and alkoxy radicals [2]. In the rea