𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetic relationships for the decomposition of cumyl hydroperoxide catalyzed by cobalt acetylacetonate in the presence of nitroxyl radicals

✍ Scribed by T. V. Sirota; O. T. Kasaikina; A. B. Gagarina

Book ID
112443634
Publisher
Springer
Year
1980
Tongue
English
Weight
441 KB
Volume
29
Category
Article
ISSN
1573-9171

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Kinetic relationships for the decomposit
Kinetic relationships for the decomposition of cumyl hydroperoxide catalyzed by cobalt acetylacetonate in the presence of nitroxyl radicals
✍ T. V. Sirota; O. T. Kasaikina; A. B. Gagarina πŸ“‚ Article πŸ“… 1980 πŸ› Springer 🌐 English βš– 441 KB

Aliphatic radicals, particularly 2,2,6,6-tetramethylpiperidin-l-oxyl, react with alkyl radicals [I]. Nitroxyls containing aromatic substituents at the N atom also react with other types of radicals. For example,4;2',2,3, is an effective scavenger of alkyl, peroxy, and alkoxy radicals [2]. In the rea

On the cobalt-catalyzed decomposition of
On the cobalt-catalyzed decomposition of tert.-butyl hydroperoxide in the presence of some five-membered heterocycles
✍ J. A. Bigot πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 316 KB

## Abstract The cobalt‐catalyzed decomposition of __tert.__‐butyl hydroperoxide in the presence of a number of five‐membered heterocycles is described. With tetrahydrofuran displacement of the alpha‐hydrogen atom by a peroxy group is observed; with furan and pyrrole 1.4 addition of peroxy radicals