## Abstract In this paper the Cu(II)βbisβ(glycinato) complex has been analysed in solution by applying a combined approach of multifrequency EPR and DFT/PCM calculations. The accuracy in the determination of magnetic parameters has been reached by the use of a unique simulation program (COSMOS) for
Stereoselectivity in the Fe(II)/Cu(II)-Mediated Homolytic Decomposition of the cis- and trans-Isomers of Pinane Hydroperoxide.
β Scribed by H. E. B. Lempers; R. A. Sheldon; K. A. D. Swift
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
Kinetics of the Cu(I1) ion-mediated acid decomposition of tris(dimethylg1yoximato)nickelate(IV), Ni(dmg);-(dmg2-= dimethylglyoximate dianion), are reported in aqueous medium in the range of 3.6 < pH < 6.6 a t 35OC and p = 0.57M. The pseudo-first-order rate constants of the disappearance of Ni(1V) (h
The decompositions of the following poly(vinyl chloride) models were investigated in the gas phase: trans-l,3-dichloro-l-pentene (in the range 310-380Β°), trans-5-chloro-3-heptene (296-357Β°), cis-4-chloro-2-pentene (295-340 Β°) and racem, and meso 2,4-dichloropentane at 351 and 370 Β°. The decompositio