The reaction mechanism of controlled hydrolysis of the inorganic ring system (NPClJ,NSOCl in the presence of KCl and 18-crown4 has been revised and is explained from steric constraints rather than from electronic considerations. The X-ray structure of one of the hydrolysis products, [KC12H2406] i-[N
The crystal structure of NPCl2(NSOCl)2
β Scribed by van de Grampel, J. C. ;Vos, A.
- Book ID
- 117856584
- Publisher
- International Union of Crystallography
- Year
- 1969
- Weight
- 696 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0567-7408
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π SIMILAR VOLUMES
## Cis-NPcI,(NSOCl), (I) reacts with dimethylamine in a molar ratio of 1:2 to give four isomen'c monosubstituted compounds N&S202C13NMe2; the position of the substituent depends strongly on the solvent. The second reaction step leads to three isomeric bis(dimethylamino) derivatives. Furthermore, two
The compounds trans-NPCl,-.guMe,)n(NSOPh),(n = 0-2) and NzP,C~-,(NM&NSOPh(n = 0-4), were prepared from their chloro-precursors. The substitution follows a completely non-geminal pathway, and all possible isomers are formed. The observed relative abundance of these isomers shows that the phenyl group