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The crystal structure of NPCl2(NSOCl)2

✍ Scribed by van de Grampel, J. C. ;Vos, A.


Book ID
117856584
Publisher
International Union of Crystallography
Year
1969
Weight
696 KB
Volume
25
Category
Article
ISSN
0567-7408

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πŸ“œ SIMILAR VOLUMES


Mechanism of the controlled hydrolysis o
✍ Herman Winter; Auke Meetsma; Johan C. van de Grampel; Anthony L. Spek πŸ“‚ Article πŸ“… 1994 πŸ› John Wiley and Sons 🌐 English βš– 463 KB

The reaction mechanism of controlled hydrolysis of the inorganic ring system (NPClJ,NSOCl in the presence of KCl and 18-crown4 has been revised and is explained from steric constraints rather than from electronic considerations. The X-ray structure of one of the hydrolysis products, [KC12H2406] i-[N

Derivatives of cis-NPCL2(NSOCl)2 and (NP
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## Cis-NPcI,(NSOCl), (I) reacts with dimethylamine in a molar ratio of 1:2 to give four isomen'c monosubstituted compounds N&S202C13NMe2; the position of the substituent depends strongly on the solvent. The second reaction step leads to three isomeric bis(dimethylamino) derivatives. Furthermore, two

Derivatives of cis-NPCl2(NSOCl)2 and (NP
✍ B. de Ruiter; J. C. van de Grampel πŸ“‚ Article πŸ“… 1981 πŸ› John Wiley and Sons 🌐 English βš– 434 KB

The compounds trans-NPCl,-.guMe,)n(NSOPh),(n = 0-2) and NzP,C~-,(NM&NSOPh(n = 0-4), were prepared from their chloro-precursors. The substitution follows a completely non-geminal pathway, and all possible isomers are formed. The observed relative abundance of these isomers shows that the phenyl group