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Mechanism of the controlled hydrolysis of (NPCl2)2NSOCl: Crystal and molecular structure of [KC12H24O6]+[NHPO2NPCl2NSOCl]−

✍ Scribed by Herman Winter; Auke Meetsma; Johan C. van de Grampel; Anthony L. Spek

Publisher: John Wiley and Sons
Year: 1994
Tongue: English
Weight: 463 KB
Volume: 5
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.520050405

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✦ Synopsis

The reaction mechanism of controlled hydrolysis of the inorganic ring system (NPClJ,NSOCl in the presence of KCl and 18-crown4 has been revised and is explained from steric constraints rather than from electronic considerations. The X-ray structure of one of the hydrolysis products, [KC12H2406] i-[NHPO2NPCl2NSOC2]-, shows a dimeric structure of two centrosymmetrically related formula units kept together by hydrogen bridges and K . . . 0 coordi-

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