The preparation of complex 1 . ~~4 and its crystal structure analysis have both been reported [S.Xl. The synthesis of the N-methylated nickel chelates roc-5.6 will be reported at a later date. In contrast to ruc-4[8], rw-5,6 are 1101 oxygen-sensitive. ## Cation Inclusion within the Mixed-Valence
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Syntheses and 31P NMR Studies of Cyclic Oxothiomolybdate(V) Molecular Rings: Exchange Properties and Crystal Structures of the Monophosphate Decamer [(H2PO4)Mo10S10O10(OH)11(H2O)2]2− and the Diphosphate Dodecamer [(HPO4)2Mo12S12O12(OH)12(H2O)2]4−
✍ Scribed by Emmanuel Cadot; Bernadette Salignac; Thierry Loiseau; Anne Dolbecq; Francis Sécheresse
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 213 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0947-6539
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Two coordination polymers 1 ϱ {[Cd(phen)](C 6 H 8 O 4 ) 3/3 } (1) and 1 ϱ {[Cd(phen)](C 7 H 10 O 4 ) 3/3 } • 2H 2 O (2) were structurally characterized by single crystal X-ray diffraction methods. In 1 (C2/ c (no. 15), a ϭ 16.169(2) A ˚, b ϭ 15.485(2) A ˚, c ϭ 14.044(2) A ˚, β ϭ 112.701(8)°, U ϭ 324