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The crystal structure of La4[Re2]O10, a fluorite-related structure containing rhenium doublets

โœ Scribed by Waltersson, K.


Book ID
117860009
Publisher
International Union of Crystallography
Year
1976
Weight
541 KB
Volume
32
Category
Article
ISSN
0567-7408

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new title compound are obtained from a mixture of La2O3, B2O3, and LaF3 in the molar ratio 5:6:2 (Walker-type multianvil apparatus, 6 GPa, 1300 ยฐC, 10 min). La4B4O11F2 crystallizes in the monoclinic space group P21/c with Z = 8. The crystal structure contains BO3 groups connected by BO4 tetrahedra v