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The crystal structure of Ca6Eu2Na2(PO4)6F2

โœ Scribed by I. Mayer; S. Cohen

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
275 KB
Volume
48
Category
Article
ISSN
0022-4596

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Crystal Structure and Polarized Raman Sp
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The crystal structure of a new apatite Ca 6 Sm 2 Na 2 (PO 4 ) 6 F 2 has been determined using 842 independent re6ections (R โ€ซุโ€ฌ 0.059, R w โ€ซุโ€ฌ 0.076). The unit cell constants are a โ€ซุโ€ฌ 9.3895(3) A > , c โ€ซุโ€ฌ 6.8950(4) A > with P6 3 /m space group. The structure contains disordered cations in both the

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The cell volume was calculated to be 3374.12(9) A s 3 , and the density was calculated to be 1.565 Mg/m 3 . The single crystal structure was also solved at ุŠ60ยฐC. The low temperature crystal data were a โ€ซุโ€ฌ 25.3961(3) A s , b โ€ซุโ€ฌ 7.06480(10) A s , and c โ€ซุโ€ฌ 20.22160(10) A s , โ€ซุโ€ฌ 113.431(1)ยฐ, Z โ€ซุโ€ฌ