Synthesis and crystal structure of Ca(VO)2(PO4)2
โ Scribed by K.H. Lii; B.R. Chueh; H.Y. Kang; S.L. Wang
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 946 KB
- Volume
- 99
- Category
- Article
- ISSN
- 0022-4596
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Synthesis and Crystal Structure of a Barium Zinc Vanadyl Phosphate, BaZn(VO)(PO4)2, Containing ((VO)PO4) Layers. -Single crystals of the title compound are prepared by solid state reaction of a prereacted mixture of BaCO3 and P2O5 (800 โข C, 24 h, air) with ZnO, V2O3, and V2O5 (780 โข C, 72 h, evacua
The 5rst examples of vanadium gallophosphates, Rb[(VO)(H2O)Ga(PO4)2] and Cs[(VO)(H2O)Ga(PO4)2] have been synthesized using hydrothermal methods, from XVO3 (X โซุโฌ Rb, Cs), Ga2O3, H3PO4, H2PO3F, and an organic species. The phases are isostructural and have a three-dimensional anionic vanadium gallopho