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The correlation of regiochemistry with structure in the S RN 1 reaction of aci -nitronates with p -nitrobenzylic substrates

✍ Scribed by Norris, RK; Randles, D


Book ID
121211040
Publisher
Commonwealth Scientific and Industrial Research Organisation Publishing
Year
1982
Tongue
English
Weight
623 KB
Volume
35
Category
Article
ISSN
0004-9425

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ethyl S- (2,4,6-trinitrophenyl) dithiocarbonate [1] and a stepwise path through a tetrahedral intermediate in the other reactions [2,3]. In the reaction of O-ethyl Sphenyl dithiocarbonate the zwitterionic tetrahedral intermediate formed by the amine attack can be deprotonated to yield an anionic int