## Abstract The kinetics of the oxidation of functionalized organic compounds of atmospheric relevance by the hydroxyl radical (OH) was measured in the aqueous phase. Competition kinetics, using the thiocyanate anion (SCN^β^) as competitor, was applied using both a laser flash photolysis long path
Rate constants for the reaction of oxygen(1-) radicals with organic substrates in aqueous solution
β Scribed by Neta, P.; Schuler, Robert H.
- Book ID
- 127003173
- Publisher
- American Chemical Society
- Year
- 1975
- Tongue
- English
- Weight
- 709 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0022-3654
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π SIMILAR VOLUMES
The kinetics of the acqueous-phase reactions of the free radicals .OH, .Cl,, and SO; . with the halogenated acetates, CHzFCOO-, CHF2COO-, CF3COO-, and with CHzClC00-, CHClzC00-, CC13COOwere investigated. Generally, the reactivity decreases with increasing halogen substitution and is in the order k(.
## Abstract The decay of photochemically generated __tert__βbutyl radicals in methylcyclopentane solutions containing chloroform is studied by timeβresolved ESR spectroscopy. In the pure solvent it perfectly follows the secondβorder rate law for radical selfβtermination. Increasing chloroform conce