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The Construction of P−O/P−N Ligands on Platinum and Palladium

✍ Scribed by Paola Bergamini; Valerio Bertolasi; Federico Milani

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
161 KB
Volume
2004
Category
Article
ISSN
1434-1948

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✍ Herbert Motschi; Paul S. Pregosin; Luigi M. Venanzi 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 German ⚖ 561 KB

NH2(CH&CH3 and (for Pt) C2H4. For both metals, the NMR. parameters depend on the trans-influence of the ligand L. The values 1J(195Pt, 15N) vary from 138 to 336 Hz and can be shown to correlate with the values 1J(195Pt, 31P) in the complexes trans-[PtCl,(PBu!j)L]. There is a linear relation between