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Palladium(II) Complexes with P,N- and C,N-Ligands as Catalysts for the Heck Reaction.

✍ Scribed by Thomas Schultz; Norbert Schmees; Andreas Pfaltz

Publisher
John Wiley and Sons
Year
2005
Weight
17 KB
Volume
36
Category
Article
ISSN
0931-7597

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An N-C-N Pincer Palladium Complex as an
An N-C-N Pincer Palladium Complex as an Efficient Catalyst Precursor for the Heck Reaction
✍ Kazuhiro Takenaka; Yasuhiro Uozumi πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 146 KB πŸ‘ 2 views

## Abstract The Heck reaction of iodobenzene and methyl acrylate took place smoothly in NMP at 140 °C in the presence of 1β€…mol ppb of the pincer palladium complex [4‐__tert__‐butyl‐2,6‐bis{(3__R__,7a__S__)‐2‐phenylhexahydro‐1__H__‐pyrrolo[1,2‐__c__]imidazole‐1‐on‐3‐yl}phenyl]chloropalladium to give