Palladium(II) complexes with P,N- and C,N-ligands as catalysts for the Heck reaction
✍ Scribed by Thomas Schultz; Norbert Schmees; Andreas Pfaltz
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 152 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0268-2605
- DOI
- 10.1002/aoc.745
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The Heck reaction of iodobenzene and methyl acrylate took place smoothly in NMP at 140 °C in the presence of 1 mol ppb of the pincer palladium complex [4‐__tert__‐butyl‐2,6‐bis{(3__R__,7a__S__)‐2‐phenylhexahydro‐1__H__‐pyrrolo[1,2‐__c__]imidazole‐1‐on‐3‐yl}phenyl]chloropalladium to give
## Abstract Imidazole and imidazoline (dihydroimidazole) derivatives can serve as efficient and simple ligands for the palladium‐catalyzed Mizoroki–Heck reaction. Among the imidazole and imidazoline derivatives in our investigations, the 2‐methylimidazoline‐palladium(II) chloride complex exhibited