Palladium N-Methylimidazolium Supported Complexes as Efficient Catalysts for the Heck Reaction.
โ Scribed by Belen Altava; M. Isabel Burguete; Eduardo Garcia-Verdugo; Naima Karbass; Santiago V. Luis; Amrit Puzary; Victor Sans
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 25 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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๐ SIMILAR VOLUMES
## Abstract A polymerโsupported macrocyclic Schiff base palladium complex has been synthesized. In the Heck reaction of aryl iodides and bromides with ethyl acrylate or styrene, the complex has been proved to give the corresponding products in good to excellent yields. The reaction proceeded smooth
## Abstract The Heck reaction of iodobenzene and methyl acrylate took place smoothly in NMP at 140โยฐC in the presence of 1โ mol ppb of the pincer palladium complex [4โ__tert__โbutylโ2,6โbis{(3__R__,7a__S__)โ2โphenylhexahydroโ1__H__โpyrrolo[1,2โ__c__]imidazoleโ1โonโ3โyl}phenyl]chloropalladium to give