The Conjugative Interaction between π-Orbitals and Walsh-e-Orbitals in Bullvalene and Related Systems
✍ Scribed by P. Bischof; R. Gleiter; E. Heilbronner; V. Hornung; G. Schröder
- Publisher
- John Wiley and Sons
- Year
- 1970
- Tongue
- German
- Weight
- 790 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Mass spectra of the fluorosulfates could not be obtained, since decomposition and polymerisation took place.
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## Abstract The photoelectron spectra of spiro[3.4]octane (**1**), spiro[3.4]octene‐5 (**2**), spiro[3.4]‐octa‐5,7‐diene (**3**), spiro[4.4]nonene‐2 (**4**) and spiro[4.4]nona‐2,4‐diene (**5**) have been recorded. The first bands of these spectra are correlated with orbitals which are π‐orbitals, _
## Abstract Photoelectron spectra of __endo__‐ and __exo__‐cyclopropano‐norbornene ( = __endo__‐ and __exo__‐tricyclo[3.2.1.0^2.4^]octa‐6‐ene) show that a significant homoconjugation exists between the π‐orbital of the double bond and the symmetric __Walsh__‐__es__‐orbital of the cyclopropane ring