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The Conjugative Interaction between π-Orbitals and Walsh-e-Orbitals in Bullvalene and Related Systems

✍ Scribed by P. Bischof; R. Gleiter; E. Heilbronner; V. Hornung; G. Schröder


Publisher
John Wiley and Sons
Year
1970
Tongue
German
Weight
790 KB
Volume
53
Category
Article
ISSN
0018-019X

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✦ Synopsis


Mass spectra of the fluorosulfates could not be obtained, since decomposition and polymerisation took place.


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## Abstract The photoelectron spectra of spiro[3.4]octane (**1**), spiro[3.4]octene‐5 (**2**), spiro[3.4]‐octa‐5,7‐diene (**3**), spiro[4.4]nonene‐2 (**4**) and spiro[4.4]nona‐2,4‐diene (**5**) have been recorded. The first bands of these spectra are correlated with orbitals which are π‐orbitals, _

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## Abstract Photoelectron spectra of __endo__‐ and __exo__‐cyclopropano‐norbornene ( = __endo__‐ and __exo__‐tricyclo[3.2.1.0^2.4^]octa‐6‐ene) show that a significant homoconjugation exists between the π‐orbital of the double bond and the symmetric __Walsh__‐__es__‐orbital of the cyclopropane ring