✦ LIBER ✦
A Photoelectron-spectroscopic investigation of the Homoconjugative Interaction between π- and Walsh-Orbitals in endo- and exo-Cyclopropano-norbornene
✍ Scribed by P. Bischof; E. Heilbronner; H. Prinzbach; H. D. Martin
- Publisher
- John Wiley and Sons
- Year
- 1971
- Tongue
- German
- Weight
- 511 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Photoelectron spectra of endo‐ and exo‐cyclopropano‐norbornene ( = endo‐ and exo‐tricyclo[3.2.1.0^2.4^]octa‐6‐ene) show that a significant homoconjugation exists between the π‐orbital of the double bond and the symmetric Walsh‐es‐orbital of the cyclopropane ring in the exo‐isomer, whereas the interaction is negligeable in the endo‐derivative.