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Interaction between the Nonbonding Orbitals of α-Dicarbonyl Systems and π or Walsh Orbitals

✍ Scribed by Prof. Dr. Rolf Gleiter; Dipl.-Ing. Richard Bartetzko; Dr. Peter Hofmann; Prof. Dr. Hans-Dieter Scharf

Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
206 KB
Volume
16
Category
Article
ISSN
0044-8249

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A Photoelectron-spectroscopic investigat
A Photoelectron-spectroscopic investigation of the Homoconjugative Interaction between π- and Walsh-Orbitals in endo- and exo-Cyclopropano-norbornene
✍ P. Bischof; E. Heilbronner; H. Prinzbach; H. D. Martin 📂 Article 📅 1971 🏛 John Wiley and Sons 🌐 German ⚖ 511 KB

## Abstract Photoelectron spectra of __endo__‐ and __exo__‐cyclopropano‐norbornene ( = __endo__‐ and __exo__‐tricyclo[3.2.1.0^2.4^]octa‐6‐ene) show that a significant homoconjugation exists between the π‐orbital of the double bond and the symmetric __Walsh__‐__es__‐orbital of the cyclopropane ring