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The conformational equilibrium in N,N′-dimethylhexahydropyrimidines

✍ Scribed by F.G. Riddell; D.A.R. Williams

Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
94 KB
Volume
12
Category
Article
ISSN
0040-4039

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## Recent investigations of a variety of substituted N-methylpiperidines indicate that the N-methyl group of g-methylpiperidine prefers the equatorial over the axial orientation by about -2.5 to 3.0 kcal/mol,1-5 a value considerably higher then that found in methylcyclohexane. 6,7 we now report on