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Spectroscopic investigation of conformational equilibrium in N-chloropiperidine

โœ Scribed by O. S. Anisimova; Yu. A. Pentin; L. G. Yudin


Publisher
Springer US
Year
1968
Tongue
English
Weight
330 KB
Volume
8
Category
Article
ISSN
0021-9037

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The Conformational Equilibrium in N,Nโ€ฒ-D
โœ F.A.L. Anet; Issa Yavari ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 225 KB

## Recent investigations of a variety of substituted N-methylpiperidines indicate that the N-methyl group of g-methylpiperidine prefers the equatorial over the axial orientation by about -2.5 to 3.0 kcal/mol,1-5 a value considerably higher then that found in methylcyclohexane. 6,7 we now report on