Molecular hydrogen is observed to be one of the major primary products in the 193 nm photodissociation of phenylstlane. A two-channel dissociation mechanism is proposed, yielding PhSiH + H, and SiH, + PhH with the former predominant. The implications of this observation for experiments which utilise
The concerted photodissociation of azomethane at 193 nm
โ Scribed by Tatsuo Gejo; Peter Felder; J. Robert Huber
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 807 KB
- Volume
- 195
- Category
- Article
- ISSN
- 0301-0104
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
We report the rotational and vibrational quantum state distributions of the CN (X 2,~ +) product formed in the 193 nm photolysis of acrylonitrile (vinyl cyanide). The CN product is formed in v = 0 and v = I with relative populations of 0.86 and 0.14, respectively. The rotational distributions in bot
A molecular beam of SO\* has been photodissociated at I93 nm to measure both the translational energy and angular distributions, from which it is concluded that the photodissociation is predissociative and that the vibrational population is peaked at un =2.