A molecular beam of SO\* has been photodissociated at I93 nm to measure both the translational energy and angular distributions, from which it is concluded that the photodissociation is predissociative and that the vibrational population is peaked at un =2.
Photodissociation of molecular beams of SO2 at 193 nm
โ Scribed by Masahiro Kawasaki; Kazuo Kasatani; Hiroyasu Sato; Hisanori Shinohara; Nobuyuki Nishi
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 486 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0301-0104
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The 193 nm photodissociation of the isotopomers SOz, SO: and SOO' (with O\*= '\*O) was studied by high-resolution photofragment translational spectroscopy. The translational energy distributions P(&) of the fragment pairs SOtO, SO'tff, SOt(T and SO\*+0 were determined from systematic analysis of the
A molecular beam of C,F,CI was photolyzed using an excimer iaser at 193 nm. Measurements of time-of-flight dtstributions of the Cl photofragment revealed a prominent fluorination effect on the dissociation process, namely a large reduction of the kinetic energy of the fragments. The dominant process