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Photodissociation channels for pentafluorochlorobenzene excited at 193 nm in molecular beams

โœ Scribed by Teijiro Ichimura; Yuji Mori; Hisanori Shinohara; Nobuyuki Nishi

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
439 KB
Volume
125
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

A molecular beam of C,F,CI was photolyzed using an excimer iaser at 193 nm. Measurements of time-of-flight dtstributions of the Cl photofragment revealed a prominent fluorination effect on the dissociation process, namely a large reduction of the kinetic energy of the fragments. The dominant process is dissociation after th~rmal~~tion to the ground state.

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