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Three dissociation channels for p-dichlorobenzene excited at 193 nm in molecular beams

✍ Scribed by Teijiro Ichimura; Yuji Mori; Hisanori Shinohara; Nobuyuki Nishi

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 373 KB
Volume: 122
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)85477-4

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✦ Synopsis

A molecular beam or p-CIC,H,CI was photolyred using an excimer laser a~ 193 nm. Measurements ol' time-of-flight distribukms of the Cl photorragmenl suggested the presence of three diKercn1 dissociation processes: direct photodissociation. predissociation presumably through non-lhennalized vibralionally excited lriplel levels and predissociarion probably abler

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Photodissociation channels for pentafluorochlorobenzene excited at 193 nm in molecular beams

✍ Teijiro Ichimura; Yuji Mori; Hisanori Shinohara; Nobuyuki Nishi 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 439 KB

A molecular beam of C,F,CI was photolyzed using an excimer iaser at 193 nm. Measurements of time-of-flight dtstributions of the Cl photofragment revealed a prominent fluorination effect on the dissociation process, namely a large reduction of the kinetic energy of the fragments. The dominant process