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The Concept of Docking and Protecting Groups in Biohydroxylation

✍ Scribed by Anna de Raadt; Herfried Griengl; Hansjörg Weber

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
165 KB
Volume
7
Category
Article
ISSN
0947-6539

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ChemInform Abstract: The Concept of Dock
ChemInform Abstract: The Concept of Docking/Protecting Groups in Biohydroxylation.
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Chiral Auxiliaries as Docking/Protecting
Chiral Auxiliaries as Docking/Protecting Groups in Biohydroxylation: The Hydroxylation of Enantiopure Spirooxazolidines Derived from Cyclopentanone Using Beauveria bassiana ATCC 7159
✍ Anna de Raadt; Barbara Fetz; Herfried Griengl; Markus Florian Klingler; Irene Ko 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 459 KB

The aim of this work was to explore the scope and limitations of chiral docking/protecting groups as chiral auxiliaries in the biohydroxylation of unactivated methylene groups. As a model compound, cyclopentanone 1 was reacted with a range of enantiomerically pure amino alcohols 2a-n as well as 7a a