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ChemInform Abstract: Chiral Auxiliaries as Docking/Protecting Groups: Biohydroxylation of Selected Ketones with Beauveria bassiana ATCC 7159.

✍ Scribed by Anna de Raadt; Barbara Fetz; Herfried Griengl; Markus Florian Klingler; Birgit Krenn; Kurt Mereiter; Dieter Franz Muenzer; Peter Plachota; Hansjoerg Weber; Robert Saf

Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
33
Category
Article
ISSN
0931-7597

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Chiral Auxiliaries as Docking/Protecting
Chiral Auxiliaries as Docking/Protecting Groups in Biohydroxylation: The Hydroxylation of Enantiopure Spirooxazolidines Derived from Cyclopentanone Using Beauveria bassiana ATCC 7159
✍ Anna de Raadt; Barbara Fetz; Herfried Griengl; Markus Florian Klingler; Irene Ko 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 459 KB

The aim of this work was to explore the scope and limitations of chiral docking/protecting groups as chiral auxiliaries in the biohydroxylation of unactivated methylene groups. As a model compound, cyclopentanone 1 was reacted with a range of enantiomerically pure amino alcohols 2a-n as well as 7a a