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The Comparative Activities of Metal Ions in Promoting Pyridoxal-catalyzed Reactions of Amino Acids 1

✍ Scribed by Longenecker, J. B.; Snell, Esmond E.

Book ID
127335515
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
466 KB
Volume
79
Category
Article
ISSN
0002-7863

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## Abstract Enantioselective synthesis of phenylalanine was performed by reacting phenylpyruvic acid with pyridoxamine followed by ketimine‐aldimine isomerization of the __Schiff__ base formed catalyzed by an optically active copper (II)‐complex. By UV and CD measurements it was shown that the enan